SAFETY DATA SHEET

F9109 POND PRO MOISTURE CURE LIQUID RUBBER BLACK
This Safety Data Sheet contains information concerning the potential risks to those involved in handling, transporting and working with the material, as well as describing potential risks to the consumer and the environment. This information must be made available to those who may come into contact with the material or are responsible for the use of the material. This Safety Data Sheet is prepared in accordance with formatting described in the REACH Regulation (EC) No 1907/2006, and described in CLP Regulation (EC) No 1272/2008.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 | Product identifier F9109POND PRO MOISTURE CURE LIQUID RUBBER BLACK |
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1.2 | Relevant identified uses of the substance or mixture and uses advised against Liquid moisture cure black rubber | |||
1.3 | Details of the supplier of the safety data sheet Company Name: Pondpro Address: 494 Bridgeport Ave Address: Suite 101-342, Shelton CT 06484 Tel: 909-752-0220 Fax: 702-977-2936 |
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1.4 | Emergency telephone number In case of emergency Tel. Chemtrec: 800-424-9300 |
SECTION 2: Hazards Identification
2.1 Classification of the substance or mixture
Classification in accordance with the Dangerous Preparations Directive 1999/45/EC
Xi; R36/38
R43
R10
R67
N; R51/53
Classification in accordance with the Classification Labelling and Packaging Regulation EC (no) 1272/2008
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Skin Sens. 1 H317
STOT SE Cat. 3 H336
Aquatic Chronic Cat, 2 H411
Flammable Liquid Cat. 3, H226
2.2 Label elements
Labelling in accordance with the Classification Labelling and Packaging Regulation EC (no) 1272/2008
WARNING
H315 Causes skin irritation
H319 Causes serious eye irritation
H317 May cause an allergic skin reaction
P280 Wear protective gloves/protective clothing/eye protection/face protection.
H336 May cause drowsiness or dizziness
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/container as hazardous waste
P210 Keep away from heat/sparks/open flames/hot surfaces – no smoking
P271 Use only outdoors or in a well ventilated area
P403 + P233 Store in a well ventilated area
2.3 Other hazards
No physical hazards are anticipated.
Expected to be irritant.
SECTION 3: Composition
3.1 Substances
Not applicable, product is a mixture
3.2 Mixtures
A mixture of polymers, solvents and additives.
Name | CAS No. | Concentration % w/w | Classification | ||||||
Polyester Resin Modified | N/A | >25% | Not Classified | ||||||
Hydroxy terminated linear polyester polyol | N/A | <5.0% | Not Classified | ||||||
4-Chloro-alpha…alpha…alpha - trifluorotoluene | 98-56-6 | >20.0%/td> | Xi; R36/38, R43 DSD 67/548/EEC Skin Irrit. 2 H315, Eye Irrit. 2 H319 Skin Sens. 1 H317 CLP 1272/2008 |
See section 16 for full description of R phrases and H statements.
SECTION 4: First Aid Measures
4.1 Description of first aid measures
EYE CONTACT: Rinse thoroughly with water for several minutes, whilst gently holding the eyelids open. Obtain medical attention if signs of discomfort.
INHALATION: Remove from exposure and keep warm and at rest. If breathing becomes difficult call a doctor. If breathing stops, begin artificial respiration and seek immediate medical attention.
SKIN CONTACT: Remove contaminated clothing. Wash off with soap and water. Seek medical attention if irritation occurs. Wash contaminated clothing before re-use.
INGESTION: If swallowed, rinse mouth with water. Do NOT induce vomiting. If vomiting occurs, keep head below hips to prevent aspiration of liquid into the lungs. Seek immediate medical attention.
4.2 Most important symptoms and effects, both acute and delayed
EYES: Redness, watering
INHALATION: Irritation of the mouth, nose and throat, coughing.
INGESTION: Irritation of the mouth and throat. Nausea, discomfort.
SKIN: Redness, irritation, rash. Chronic exposure may result in allergic skin reactions.
4.3 Indication of any immediate medical attention and special treatments needed
Symptomatic treatment as required
SECTION 5: Firefighting Measures
5.1 Extinguishing media
Small fires: Foam, CO2, dry chemical
Large fires: Water fog, foam, CO2, dry chemical
5.2 Special hazards arising from the substance or mixture
Decomposition products will include oxides of carbon and nitrogen, incomplete combustion products.
5.3 Advice for fire fighters
Prevent run-off from fire from entering water courses and sewers. Firefighters should use standard protective equipment and in enclosed spaces, positive pressure self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed containers.
SECTION 6: Firefighting Measures
6.1 Personal precautions, protective equipment and emergency procedures
Remove all ignition sources and evacuate unnecessary personnel from the area. Ventilate the area if possible. Wear suitable protective clothing including solvent resistant gloves and coveralls. If vapour concentrations are high, respiratory protective equipment may be required. See section 8 for more information.
6.2 Environmental precautions
Prevent entry into sewers and watercourses. If product enters sewers or watercourses, inform the appropriate environmental authorities.
6.3 Methods and materials for containment and clearing up
Small spills: Remove all ignition sources. Absorb spillage in a non-combustible absorbent, e.g. sand or vermiculite, and place in a suitable container for disposal.
Large spills: Remove all ignition sources. Contain spill and cover if possible to reduce evaporation. Mix spillage with a suitable non-combustible absorbent, e.g. sand or earth, and place in a suitable container for disposal.
6.4 References to other sections
See sections 8 and 13 for further advice on protective clothing and disposal.
SECTION 7: Handling and Storage
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Use only in well-ventilated areas. Avoid contact with all ignition sources, including hot surfaces.
7.2 Conditions for safe storage, including any incompatibilities
Store in a well-ventilated, bonded area, away from all ignition sources. Keep out of direct sunlight. Vapours are heavier than air and may accumulate in low-lying areas and below ground areas such as ducts and sewers.
7.3 Specific end uses
No industrial or sector specific guidance available.
SECTION 8. Exposure Controls/Personal Protection
8.1 Control parameters
No exposure limits available.
8.2 Exposure controls
Engineering controls
Adequate ventilation should be provided so that exposure limits are not exceeded. Use explosion-proof ventilation equipment.
Respiratory protection
Use only in well-ventilated area. If exposure levels are likely to exceed the OEL then suitable respiratory protection will be required.
Hand Protection
Wear suitable chemical resistant gloves recommended for use with hydrocarbon solvent. Nitrile gloves may be suitable, but glove manufacturers’ specifications should always be checked first. Natural rubber gloves are not suitable. Change gloves in accordance with manufacturer recommendations. If gloves are damaged during use, remove immediately and wash hands before replacing with new gloves.
Eye protection
Wear suitable eye protection, meeting the requirements of BS EN166 3, when handling this product.
Skin protection
Aprons or coveralls are recommended. These should be changed after use or if contaminated. Wash before re-use.
Environmental Exposure Controls
Take suitable measures to prevent entry into drains, sewers and watercourses.
SECTION 9: Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance: | Black viscous liquid | |||
Odor: | Mild solvent odor | |||
Odor threshold: | No data available | |||
pH: | Not applicable | |||
Melting point: | No data available | |||
Boiling point: | No data available | |||
Flashpoint: | 109°F | |||
Evaporation rate: | No data available | |||
Flammability (gas, solid): | Not applicable | |||
Upper/lower flammability limits: | Not applicable | |||
Vapor pressure: | No data available | |||
Vapor density: | Heavier than air | |||
Relative density: | 11.2 lbs./gallon | |||
Solubility in water: | Insoluble | |||
Solubility in other solvents: | No data available | |||
Partition coefficient (log Kow): | No data available | |||
Autoignition temperature: | No data available | |||
Decomposition temperature: | No data available | |||
Viscosity: | No data available | |||
Explosive properties: | Not classified as explosive | |||
Oxidizing properties: | Not classified as explosive | |||
Oxidizing properties: | Not classified as explosive |
9.2 Other information
VOC content: | 12 g/l |
SECTION 10: Stability and Reactivity
10.1 Reactivity
Not considered a reactive material.
10.2 Chemical stability
This material is stable under expected conditions of use.
10.3 Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Strong oxidizers.
10.6 Hazardous decomposition products
Material does not decompose under normal conditions of use. See section 5 for fire decomposition products.
SECTION 11: Toxicological Information
11.1 Information on toxicological effects
This product has not been tested. Judgements on the expected toxicity of this product have been made based upon consideration of its major components.
(a) acute toxicity | Not expected to be acutely toxic, based on consideration of the components. Acute Toxicity Estimate (ATE) > 2000 mg/kg | |||
(b) skin corrosion/irritation | Expected to be irritating to skin, based on consideration of the components. | |||
(c) serious eye damage/irritation | Expected to be irritating to eyes, based on consideration of the components. | |||
(d) respiratory/skin sensitization | Expected to be sensitizing, based on consideration of the components. | |||
(e) germ cell mutagenicity | Not expected to be mutagenic. | |||
(f) carcinogenicity | Contains no components considered to be carcinogenic above thresholds of concern. | |||
(g) reproductive toxicity | Contains no components considered to be hazardous to reproduction above thresholds of concern. | |||
(h) STOT-single exposure | Not expected to cause organ damage. The solvents present may cause narcotic effects if inhaled or ingested in large quantities. | |||
(i) STOT-repeated exposure | Not expected to cause organ damage from prolonged or repeated exposure. | |||
(j) aspiration hazard | Not expected to be an aspiration hazard. |
SECTION 12: Ecological Information
This product has not been tested. Judgements on the expected toxicity of this product have been made based upon consideration of its major components.
12.1 Toxicity
This product contains components that are considered to be toxic to aquatic organisms and may cause longterm adverse effects in the aquatic environment. Once cured the toxicity of the product is expected to decrease.
12.2 Persistence and degradability
This product is not expected to be readily biodegradable.
12.3 Bioaccumulative potential
This product is expected to have a low bioaccumulation potential.
12.4 Mobility in soil
Cured product is expected to be immobile.
12.5 Results of PBT and vPvB assessment
None of the components are known to be PBT or vPvB.
12.6 Other adverse effects
None known.
SECTION 13: Disposal Considerations
13.1 Waste treatment methods
Recover and recycle product if possible. If recovery and recycling are not possible, dispose of by incineration.
Empty containers may contain flammable residues. Do not puncture, cut or grind. Empty containers should be disposed of as hazardous waste.
Disposal should be in accordance with local and national regulations.
SECTION 14: Transport Information
ADR | IMDG | ICAO | USDOT | ||||||||
14.1 UN Number | 1287 | 1287 | 1287 | 1287 | |||||||
14.2 UN Proper shipping name | RUBBER SOLUTION | RUBBER SOLUTION | RUBBER SOLUTION | RUBBER SOLUTION NOT REGULATED | |||||||
14.3 Transport hazard class(es) | 3 | 3 | 3 | N/A | |||||||
14.4 Packing group | III | III | III | N/A | |||||||
14.5 Environmental hazards | NONE | NONE | NONE | NONE | |||||||
14.6 Special precautions for user | NONE | NONE | NONE | NONE | |||||||
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code | NONE | NONE | NONE | NONE |
SECTION 15: Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
All components are listed as existing substances in Europe
15.2 Chemical Safety Assessment
A Chemical Safety Assessment has not been carried out for this product.
SECTION 16: Other Information
Revision information:
This is a new SDS.
List of Abbreviations used in this SDS:
CAS | Chemical Abstracts Service | |||
CLP | Classification, Labelling and Packaging Regulation (EC) no 1272/2008 | |||
DSD | Dangerous Substances Directive 67/548/EEC | |||
DPD | Dangerous Preparations Directive 1999/45/EC | |||
EC | European Community/Commission | |||
PBT | Persistent, Bioaccumulative and Toxic | |||
REACH | Registration, Evaluation, Authorization and Restriction of Chemicals Regulation (EC) no 1907/2006 | |||
vPvB | very Persistent, very Bioaccumulative |
References:
ECHA CHEM database
Suppliers’ SDSs for component substances
Method used for classification of mixtures:
Ingredient based approaches
R Phrases and H Statements used in Section 3
R10 | Flammable | |||
R36/38 | Irritating to eyes and skin | |||
R37 | Irritating to respiratory system | |||
R38 | Irritating to skin | |||
R43 | May cause sensitization by skin contact | |||
R51/53 | Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment | |||
R65 | Harmful: may cause lung damage if swallowed | |||
R66 | Repeated exposure may cause skin dryness or cracking | |||
R68 | Possible risk of irreversible effects |
H226 | Flammable liquid and vapor | |||
H304 | May be fatal if swallowed and enters airways | |||
H315 | Causes skin irritation | |||
H317 | May cause an allergic skin reaction | |||
H319 | Causes serious eye irritation | |||
H335 | May cause respiratory irritation | |||
H341 | Suspected of causing genetic defects |
EUH066 Repeated exposure may cause skin dryness or cracking
Training requirements for workers
No special requirements.